Yıl 2016, Cilt 20 , Sayı 3, Sayfalar 635 - 644 2016-10-11

Zn(II) iyonlarının piromellitik dianhidrit ile modifiye edilmiş poliamin poliüre polimeri ile adsorpsiyonu
Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride

Çiğdem Özer [1] , Eda Ergin [2] , Füsun Boysan [3] , Mustafa İmamoğlu [4]


Bu çalışmada sulu çözeltilerden Zn(II) iyonlarının piromellitik dianhidrit ile modifiye edilmiş poliamin- poliüre polimeri (PMPPP) üzerine adsorpsiyonu incelenmiştir. Adsorpsiyon çalışmasına etkisi incelenen parametreler; pH, temas süresi, PMPPP dozu, Zn(II) başlangıç konsantrasyonudur. Langmuir ve Freundlich izoterm modelleri kullanılarak analiz edilen Zn(II) adsorpsiyonunun deneysel verileri, tek tabakalı adsorpsiyonu ifade eden Langmuir izotermi ile daha yüksek uyum göstermiştir. Langmuir izotermine göre Zn(II) iyonları için PMPPP’nin maksimum adsorpsiyon kapasitesi 119.1 mg g-1 olarak hesaplanmıştır. PMPPP ile Zn(II) iyonlarının adsorpsiyon kinetiği pseudo ikinci derece modeli ile uyumlu bulunmuştur. Zn(II) adsorpsiyonu için termodinamik hesaplar prosesin ekzotermik ve kendiliğinden gerçekleşme eğiliminde olduğunu göstermiştir.

In this study, adsorption of Zn(II) ions from aqueous solutions was investigated using polyamine polyurea polymer modified with pyromellitic dianhydride (PMPPP). The parameters on the adsorption studies such as pH, contact time, PMPPP dose and initial concentration of Zn(II) were studied. The experimental data analyzed using Langmuir and Freundlich isotherm models were showed a higher compliance with the Langmuir isotherm representing the monolayer adsorption. Maximum adsorption capacity of PMPPP for Zn (II) ions was calculated to be 119.1 mg g-1 according to Langmuir isotherm. Adsorption kinetics of Zn(II) ions on PMPPP were found to consistent with second order model. Thermodynamic calculations showed that the process is exothermic and occurs spontaneously.

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Bölüm Araştırma Makalesi
Yazarlar

Yazar: Çiğdem Özer

Yazar: Eda Ergin

Yazar: Füsun Boysan

Yazar: Mustafa İmamoğlu

Tarihler

Başvuru Tarihi : 21 Haziran 2016
Kabul Tarihi : 17 Ekim 2019
Yayımlanma Tarihi : 11 Ekim 2016

Bibtex @ { saufenbilder270019, journal = {Sakarya University Journal of Science}, issn = {1301-4048}, eissn = {2147-835X}, address = {}, publisher = {Sakarya Üniversitesi}, year = {2016}, volume = {20}, pages = {635 - 644}, doi = {10.16984/saufenbilder.00606}, title = {Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride}, key = {cite}, author = {Özer, Çiğdem and Ergin, Eda and Boysan, Füsun and İmamoğlu, Mustafa} }
APA Özer, Ç , Ergin, E , Boysan, F , İmamoğlu, M . (2016). Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride. Sakarya University Journal of Science , 20 (3) , 635-644 . DOI: 10.16984/saufenbilder.00606
MLA Özer, Ç , Ergin, E , Boysan, F , İmamoğlu, M . "Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride". Sakarya University Journal of Science 20 (2016 ): 635-644 <http://www.saujs.sakarya.edu.tr/tr/issue/25594/270019>
Chicago Özer, Ç , Ergin, E , Boysan, F , İmamoğlu, M . "Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride". Sakarya University Journal of Science 20 (2016 ): 635-644
RIS TY - JOUR T1 - Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride AU - Çiğdem Özer , Eda Ergin , Füsun Boysan , Mustafa İmamoğlu Y1 - 2016 PY - 2016 N1 - doi: 10.16984/saufenbilder.00606 DO - 10.16984/saufenbilder.00606 T2 - Sakarya University Journal of Science JF - Journal JO - JOR SP - 635 EP - 644 VL - 20 IS - 3 SN - 1301-4048-2147-835X M3 - doi: 10.16984/saufenbilder.00606 UR - https://doi.org/10.16984/saufenbilder.00606 Y2 - 2019 ER -
EndNote %0 Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride %A Çiğdem Özer , Eda Ergin , Füsun Boysan , Mustafa İmamoğlu %T Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride %D 2016 %J Sakarya University Journal of Science %P 1301-4048-2147-835X %V 20 %N 3 %R doi: 10.16984/saufenbilder.00606 %U 10.16984/saufenbilder.00606
ISNAD Özer, Çiğdem , Ergin, Eda , Boysan, Füsun , İmamoğlu, Mustafa . "Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride". Sakarya University Journal of Science 20 / 3 (Ekim 2016): 635-644 . https://doi.org/10.16984/saufenbilder.00606
AMA Özer Ç , Ergin E , Boysan F , İmamoğlu M . Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride. SAUJS. 2016; 20(3): 635-644.
Vancouver Özer Ç , Ergin E , Boysan F , İmamoğlu M . Adsorption of Zn(II) ıons with polyamine polyurea polymer modified with pyromellitic dianhydride. Sakarya University Journal of Science. 2016; 20(3): 644-635.