Yıl 2016, Cilt 20 , Sayı 3, Sayfalar 565 - 571 2016-09-02

Cis-2,6-bis(2-klorofenil)-3,3-dimetilpiperidin-4-one bileşiği üzerine yapısal, spektroskopik, elektronik ve doğrusal olmayan optiksel araştırmalar
Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one

Ömer Tamer [1]


Piperidin, heterosiklik moleküller arasında en iyi bilinen yapılardan biridir. Güncel çalışmalar bu tür bileşiklerin yapı-doğrusal olmayan optiksel performans ilişkisine odaklanmaktadır. Doğrusal olmayan optik malzemelerin fiber optik iletişim ve optik sinyal işlemlerinde hayati öneme sahip oldukları bilinmektedir. Bu çalışmada, bir piperidin türevi olan cis-2,6-bis(2-klorofenil)-3,3-dimetilpiperidin-4-one (2C3DMPO) bileşiğinin yapısal, spektroskopik, elektronik ve doğrusal olmayan optik özellikleri analiz edilmiştir. 2C3DMPO için elde edilen teorik sonuçlar deneysel değerler ile iyi bir uyum içindedirler. NMR spektrumunda, elektronegatif O atomundan dolayı, C4 atomu aşağı alanda sinyal vermiştir. HOMO ve LUMO arasındaki küçük enerji aralığı, bağ ve antibağ yörüngeleri arasındaki yoğun etkileşmeler yüksek doğrusal olmayan optik özelliklerin göstergesidir.

Piperidine is one of the most recognizable structural entities among heterocyclic molecules. The current studies have been focused on structure–nonlinear optical performance relationship of such compounds. It is well known that the nonlinear optical materials play a vital role in the field of fiber optic communications and optical signal process. In this study, cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one (2C3DMPO) compound which is a piperidine derivate has been analyzed in terms of structural, spectroscopic, electronic and nonlinear optical properties. Obtained theoretical results for 2C3DMPO are in good agreement with previously reported experimental data. In NMR calculations C4 atom gives signal at downfield region due to bonding electronegative O atom. The small energy gap between HOMO and LUMO energies, and the intensive interactions between the bonding and antibonding orbitals are indicators of high nonlinear optical properties.

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Bölüm Araştırma Makalesi
Yazarlar

Yazar: Ömer Tamer

Tarihler

Başvuru Tarihi : 9 Haziran 2016
Kabul Tarihi : 17 Ekim 2019
Yayımlanma Tarihi : 2 Eylül 2016

Bibtex @ { saufenbilder270013, journal = {Sakarya University Journal of Science}, issn = {1301-4048}, eissn = {2147-835X}, address = {}, publisher = {Sakarya Üniversitesi}, year = {2016}, volume = {20}, pages = {565 - 571}, doi = {10.16984/saufenbilder.18819}, title = {Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one}, key = {cite}, author = {Tamer, Ömer} }
APA Tamer, Ö . (2016). Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one. Sakarya University Journal of Science , 20 (3) , 565-571 . DOI: 10.16984/saufenbilder.18819
MLA Tamer, Ö . "Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one". Sakarya University Journal of Science 20 (2016 ): 565-571 <http://www.saujs.sakarya.edu.tr/tr/issue/25594/270013>
Chicago Tamer, Ö . "Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one". Sakarya University Journal of Science 20 (2016 ): 565-571
RIS TY - JOUR T1 - Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one AU - Ömer Tamer Y1 - 2016 PY - 2016 N1 - doi: 10.16984/saufenbilder.18819 DO - 10.16984/saufenbilder.18819 T2 - Sakarya University Journal of Science JF - Journal JO - JOR SP - 565 EP - 571 VL - 20 IS - 3 SN - 1301-4048-2147-835X M3 - doi: 10.16984/saufenbilder.18819 UR - https://doi.org/10.16984/saufenbilder.18819 Y2 - 2019 ER -
EndNote %0 Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one %A Ömer Tamer %T Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one %D 2016 %J Sakarya University Journal of Science %P 1301-4048-2147-835X %V 20 %N 3 %R doi: 10.16984/saufenbilder.18819 %U 10.16984/saufenbilder.18819
ISNAD Tamer, Ömer . "Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one". Sakarya University Journal of Science 20 / 3 (Eylül 2016): 565-571 . https://doi.org/10.16984/saufenbilder.18819
AMA Tamer Ö . Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one. SAUJS. 2016; 20(3): 565-571.
Vancouver Tamer Ö . Structural, spectroscopic, electronic and nonlinear optical investigations on cis-2,6-bis(2-chlorophenyl)-3,3-dimethylpiperidin-4-one. Sakarya University Journal of Science. 2016; 20(3): 571-565.