Yıl 2018, Cilt 22, Sayı 6, Sayfalar 1812 - 1819 2018-12-01

METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD

Esra Altıntığ [1] , Ömer Faruk Soydan [2]

27 51

This study examines the characterization and adsorption features of silver that was added to oxygen containing activated carbons using the sol-gel method. The surface area of the silver coated activated carbon (AC/Ag) Nano-composites, which were prepared using the sol-gel method, was measured with the Braunauer-Emmett-Teller surface area calculation method according to N2 adsorption at 77 K. The microstructure and surface morphologies of the AC/Ag Nano-composite samples were examined with the use of Scanning Electron Microscope. Methylene Blue removal was performed with AC/Ag-1 with 658.488 m2/g, which had the highest surface area, and the Qmax value was calculated as 416. 66 mg/g. 

Wild chestnut, Silver, sol-gel, Activated carbon, Adsorption
  • [1] G. Mezohegyi, F.P. van der Zee, J. Font, A. Fortuny, A. Fabregat, “Towards advanced aqueous dye removal processes: a short review on the versatile role of activated carbon”, J. Environ. Manage. , vol. 102, pp.148–164, 2012.[2] Y. Guo, A.D. Rockstraw, “Physical and chemical properties of carbons synthesized from xylan, cellulose and kraft lignin by H3PO4 activation”, Carbon, vol. 44, pp. 1464-1475, 2006. [3] R.N. Khalili, M. Campbell, G. Sandi, J. Golas , “Production of Micro and Mesoporous Activated Carbon from Paper Mill Sludge”, Carbon, vol. 38, pp.1905-1915, 2000. [4] H. Deng, L. Yang, G. Tao, J. Daı, “Preparation and characterization of activated carbon from cotton stalk by microwave assisted chemical activation-Application in methylene blue adsorption from aqueous solution”, J. Hazard. Mater. Vol. 166, pp.1514-1521, 2009. [5] T.H.Liou, S. Jung, “Characteristics of microporous/mesoporous carbons prepared from rice husk under base- and acid-treated conditions”, J. Hazard. Mater. Vol. 171, pp. 693–703, 2009. [6] W. Wang, K. Xiao, T. He, L. Zhu, “Synthesis and characterization of Ag nanoparticles decorated mesoporous sintered activated carbon with antibacterial and adsorptive properties”, J. Alloy Compd. Vol. 647, pp. 1007-1012, 2015.[7] A.K. Karumuri, D.P. Oswal, H.A. Hostetler, S.M. Mukhopadhyay, “Silver nanoparticles attached to porous carbon substrates: robust materials for chemical-free water disinfection”, Mater. Lett. Vol. 109, pp. 83–87, 2013. [8] L. Pei, J. Zhou, L. Zhang, “Preparation and properties of Ag-coated activated carbon nanocomposites for indoor air quality control”, Build. Environ. Vol. 63, pp. 108-113, 2013. [9] Z. Shi, H. Zhou, X. Qing, T. Dai, Y. Lu, “Facile fabrication and characterization of poly(tetrafluoroethlene)@polypyrrole/nano-silver composite membranes with conducting and antibacterial property”, Appl. Surf. Sci.vol. 258, pp. 6359–6365, 2012.[10] K. Mallick, M.J. Witcom, M.S. Scurrell, “Polymer stabilized silver nanoparticles: a photochemical synthesis route”, J. Mater. Sci. Vol. 39, pp. 4459–4463, 2009. [11] I. Lee, S.W. Han, K. Kim, “Simultaneous preparation of SERS-active metal colloids and plates by laser ablation”, J.0 Raman Spectrosc. vol. 32, pp. 947–952, 2001. [12] H. Bönnemann, R. Richards, “Nanoscopic metal particles–synthetic methods and potential applications”, Eur. J. Inorg. Chem. vol. 10, pp. 2455–2480, 2001. [13] S. Senthilkumaar, K. Porkodi, R. Gomathi, A.G. Maheswari, N. Manonmani, “Sol gel derived silver doped nanocrystalline titania catalysed photodegradation of methylene blue from aqueous solution”, Dyes Pigments, vol. 69, pp. 22-30, 2006.[14] E. Altintig, O.F. Soydan, “Activated carbon from wild chestnut Shell upon chemical activation with phosphoric acid”, Oxid. Commun. vol. 39 (I-II), pp. 808–816, 2016. [15] E. Daneshvar, A. Vazirzadeh, A. Niazi, M. Kousha, M. Naushad, A. Bhatnagar, “Desorption of Methylene blue dye from brown macroalga: Effects of operating parameters, isotherm study and kinetic modeling”, J. Clean Produc. vol. 152, pp. 443-453, 2017. [16] M. Nasrollahzadeh, M. Atarod, B.Jaleh, M. Gandomirouzbahani, “In situ green synthesis of Ag nanoparticles on graphene oxide/TiO2 nanocomposite and their catalytic activity for the reduction of 4-nitrophenol, congo red and methylene blue”, Ceram. Int. vol. 42, pp. 8587–8596, 2016. [17] P.K.Khanna, R. Gokhale, V.V.V.S. Subbarao, A.K.Viswanath, B.K. Das, C.V.V. Satyanarayana, “PVA stabilized gold nanoparticles by use of unexplored albeit conventional reducing agent”, Mater. Chem. Phys. vol. 92 (1), pp. 229-233, 2005. [18] Y..Zhao, Z. Wang, X. Zhao, W. Li, S. Liu, “Antibacterial action of silver-doped activated carbon prepared by vacuum impregnation”, Appl. Surf. Sci. vol. 266, pp. 67–72, 2013. [19] H.Q. Tang, H.J. Feng, J.H. Zheng, J. Zhao, ” A study on antibacterial properties of Ag+-implanted pyrolytic carbon”, Surf. Coat. Technol. vol. 201, pp. 5633–5636, 2007. [20] O. Sawai, Y. Oshima, “Deposition of silver nano-particles on activated carbon using supercritical water”, J. Supercrit. Fluid. vol. 47, pp. 240–246, 2008.[21] E. Altıntıg, S. Kırkıl, “Preparation and properties of Ag-coated activated carbon nanocomposites produced from wild chestnut shell by ZnCl2 activation”, J. Taiwan Inst. Chem. Eng. vol. 63, pp. 180-188, 2016. [22] I. Langumuir, “The adsorption of gases on plane surfaces of glass, mica and platinum”, J. Am. Chem. Soc. vol. 40, pp. 1361–1403, 1918. [23] H.M.F. Freundlich, “Over the adsorption in solution”, Z. Phys. Chem.vol. A57, pp. 358–471, 1906. [24] E. Bagda, “The feasibility of using Rosa canina galls as an effective new biosorbent for removal of methylene blue and crystal violet”. Des. Water Treat. vol. 43, pp. 63-75, 2012. [25] F. Nekouei, H. Kargarzadeh, S. Nekouei, F. Keshtpour , A.S.H. Makhlouf, “Novel, facile, and fast technique for synthesis of AgCl nanorods loaded on activated carbon for removal of methylene blue dye”, Process Saf Environ. vol. 103, pp. 212–226, 2016. [26] M. Ghaedi, S.H. Heidarpour, S.N.Kokhdan, R. Sahraie, A. Daneshfar, B. Brazesh, “Comparison of silver and palladium nanoparticles loaded on activated carbon for efficient removal of Methylene blue: Kinetic and isotherm study of removal process”, Powder Technol. vol. 228, pp. 18–25, 2012. [27] T.Q. Tuan, N.V. Son, H.T.K. Dung, N.H. Luong, B.T. Thuy, N.T. Van Anh, N.D. Hoa, N.H. Hai, “Preparation and properties of silver nanoparticles loaded in activated carbon for biological and environmental applications”, J. Hazard. Mater. vol. 192, pp. 1321–1329, 2011. [28] B.Q. Han, F. .Zhang, Z.P. Feng, S.Y.Liu, S.J. Deng, Y. Wang, “A designed Mn2O3/MCM-41 nanoporous composite for methylene blue and rhodamine B removal with high efficiency”, Ceram. Int. vol. 40, pp. 8093–8101, 2014. [29] Q. .Chen, Q. Wu, “Preparation of carbon microspheres decorated with silver nanoparticles and their ability to remove dyes from aqueous solution”, J. Hazard. Mater. vol. 283, pp. 193–201, 2015.
Birincil Dil en
Konular Mühendislik
Yayımlanma Tarihi December 2018
Dergi Bölümü Araştırma Makalesi
Yazarlar

Orcid: 0000-0001-8031-2415
Yazar: Esra Altıntığ (Sorumlu Yazar)
Kurum: Sakarya University, Science and Art Faculty, Chemistry Department
Ülke: Turkey


Orcid: 0000-0002-9136-9377
Yazar: Ömer Faruk Soydan

Bibtex @araştırma makalesi { saufenbilder402500, journal = {Sakarya University Journal of Science}, issn = {1301-4048}, eissn = {2147-835X}, address = {Sakarya Üniversitesi}, year = {2018}, volume = {22}, pages = {1812 - 1819}, doi = {10.16984/saufenbilder.402500}, title = {METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD}, key = {cite}, author = {Soydan, Ömer Faruk and Altıntığ, Esra} }
APA Altıntığ, E , Soydan, Ö . (2018). METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD. Sakarya University Journal of Science, 22 (6), 1812-1819. DOI: 10.16984/saufenbilder.402500
MLA Altıntığ, E , Soydan, Ö . "METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD". Sakarya University Journal of Science 22 (2018): 1812-1819 <http://www.saujs.sakarya.edu.tr/issue/31266/402500>
Chicago Altıntığ, E , Soydan, Ö . "METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD". Sakarya University Journal of Science 22 (2018): 1812-1819
RIS TY - JOUR T1 - METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD AU - Esra Altıntığ , Ömer Faruk Soydan Y1 - 2018 PY - 2018 N1 - doi: 10.16984/saufenbilder.402500 DO - 10.16984/saufenbilder.402500 T2 - Sakarya University Journal of Science JF - Journal JO - JOR SP - 1812 EP - 1819 VL - 22 IS - 6 SN - 1301-4048-2147-835X M3 - doi: 10.16984/saufenbilder.402500 UR - http://dx.doi.org/10.16984/saufenbilder.402500 Y2 - 2018 ER -
EndNote %0 Sakarya University Journal of Science METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD %A Esra Altıntığ , Ömer Faruk Soydan %T METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD %D 2018 %J Sakarya University Journal of Science %P 1301-4048-2147-835X %V 22 %N 6 %R doi: 10.16984/saufenbilder.402500 %U 10.16984/saufenbilder.402500
ISNAD Altıntığ, Esra , Soydan, Ömer Faruk . "METHEYLENE BLUE ADSORPTION AND PREPARATION SILVER BOUND TO ACTİVATED CARBON WITH SOL-GEL METHOD". Sakarya University Journal of Science 22 / 6 (Aralık 2018): 1812-1819. http://dx.doi.org/10.16984/saufenbilder.402500