Yıl 2018, Cilt 22, Sayı 6, Sayfalar 1571 - 1575 2018-12-01

Preparation of Nano Polymeric Thiophenes and Characterization of the Structures
Nano Polimerik Tiyofenlerin Hazırlanması ve Yapılarının Karakterizasyonu

Sezen SİVRİKAYA [1] , Sefa DURMUŞ [2] , Aslıhan DALMAZ [3]

263 257

This article describes a chemical oxidative polymerization for the preparation of nano polymeric thiophene by using FeCl3 as oxidant. 2-thiophenecarboxaldehyde (2-THCA) as monomer was used at polymerization process. The structure of synthesized nano polymeric thiophene was confirmed by  scanning electron microscopy (SEM), Fourier transform infrared spectroscopy (FTIR), Thermogravimetric analysis (TGA), Raman Spectroscopy, and elemental analysis of C, H, O and S. SEM images showed that the poly(2-thiophenecarboxaldehyde) (PTHCA) was synthesized in nanoscale and had a homogeneous and smooth structure. The size of the synthesized nano particles was not more than 35 nm. Thermal analysis of nano polymeric thiophene showed thermally stable up to 512 OC. When elemental analysis results of PTHCA were examined, it was seen that the obtained data after the synthesis of nano polymeric thiophene and the determined data theoretically were agree with each other.

Bu çalışma, oksidant olarak FeCl3 kullanarak nano polimerik tiyofenin hazırlanması için kimyasal oksidatif polimerizasyonu açıklamaktadır. Polimerizasyon prosedüründe monomer olarak 2-tiyofenkarboksialdehit kullanılmıştır. Sentezlenen nano polimerik tiyofenin yapıları, taramalı elektron mikroskobu (SEM), Fourier transform infrared spektroskopisi (FTIR), Termogravimetrik analiz (TGA), Raman Spektroskopisi ve C, H, O ve S'nin elemental analizi ile doğrulanmıştır. SEM görüntüleri ile polimerin nano boyutlarda sentezlenmiş olduğu, homojen ve pürüzsüz bir yapıya sahip olduğu tespit edilmiştir. Oluşan parçacıkların boyutlarının 35 nm'den fazla olmadığı görülmüştür. Nano polimerik tiyofenin termal analizi polimerin 512 OC'ye kadar termik olarak stabil olduğunu göstermiştir. Elementel analiz sonuçları incelendiğinde, nano polimerik tiyofenin sentezi sonucu elde edilen veriler ile teorik olarak belirlenen verilerin birbiri ile uyum içerisinde olduğu görülmüştür.

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Birincil Dil en
Konular Mühendislik
Yayımlanma Tarihi December 2018
Dergi Bölümü Araştırma Makalesi
Yazarlar

Yazar: Sezen SİVRİKAYA
Kurum: DUZCE UNIV
Ülke: Turkey


Yazar: Sefa DURMUŞ
Kurum: DUZCE UNIV
Ülke: Turkey


Yazar: Aslıhan DALMAZ
Kurum: DUZCE UNIV
Ülke: Turkey


Bibtex @araştırma makalesi { saufenbilder273829, journal = {Sakarya University Journal of Science}, issn = {1301-4048}, eissn = {2147-835X}, address = {Sakarya Üniversitesi}, year = {2018}, volume = {22}, pages = {1571 - 1575}, doi = {10.16984/saufenbilder.273829}, title = {Preparation of Nano Polymeric Thiophenes and Characterization of the Structures}, key = {cite}, author = {SİVRİKAYA, Sezen and DURMUŞ, Sefa and DALMAZ, Aslıhan} }
APA SİVRİKAYA, S , DURMUŞ, S , DALMAZ, A . (2018). Preparation of Nano Polymeric Thiophenes and Characterization of the Structures. Sakarya University Journal of Science, 22 (6), 1571-1575. DOI: 10.16984/saufenbilder.273829
MLA SİVRİKAYA, S , DURMUŞ, S , DALMAZ, A . "Preparation of Nano Polymeric Thiophenes and Characterization of the Structures". Sakarya University Journal of Science 22 (2018): 1571-1575 <http://www.saujs.sakarya.edu.tr/issue/31266/273829>
Chicago SİVRİKAYA, S , DURMUŞ, S , DALMAZ, A . "Preparation of Nano Polymeric Thiophenes and Characterization of the Structures". Sakarya University Journal of Science 22 (2018): 1571-1575
RIS TY - JOUR T1 - Preparation of Nano Polymeric Thiophenes and Characterization of the Structures AU - Sezen SİVRİKAYA , Sefa DURMUŞ , Aslıhan DALMAZ Y1 - 2018 PY - 2018 N1 - doi: 10.16984/saufenbilder.273829 DO - 10.16984/saufenbilder.273829 T2 - Sakarya University Journal of Science JF - Journal JO - JOR SP - 1571 EP - 1575 VL - 22 IS - 6 SN - 1301-4048-2147-835X M3 - doi: 10.16984/saufenbilder.273829 UR - http://dx.doi.org/10.16984/saufenbilder.273829 Y2 - 2018 ER -
EndNote %0 Sakarya University Journal of Science Preparation of Nano Polymeric Thiophenes and Characterization of the Structures %A Sezen SİVRİKAYA , Sefa DURMUŞ , Aslıhan DALMAZ %T Preparation of Nano Polymeric Thiophenes and Characterization of the Structures %D 2018 %J Sakarya University Journal of Science %P 1301-4048-2147-835X %V 22 %N 6 %R doi: 10.16984/saufenbilder.273829 %U 10.16984/saufenbilder.273829
ISNAD SİVRİKAYA, Sezen , DURMUŞ, Sefa , DALMAZ, Aslıhan . "Nano Polimerik Tiyofenlerin Hazırlanması ve Yapılarının Karakterizasyonu". Sakarya University Journal of Science 22 / 6 (Aralık 2018): 1571-1575. http://dx.doi.org/10.16984/saufenbilder.273829