Year 2020, Volume 24 , Issue 1, Pages 205 - 219 2020-02-01

Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP

Uğur SOYKAN [1]


This study paves to way to investigate the fundamental characteristics including the crystalline melting temperature, percent crystallinity, crystal structure, unit cell parameters, crystal size, mechanical behaviour, ultimate strength, Modulus and impact strength in the IPP based composites formed by blending of IPP with the varying content levels (5, 10, 15, 20 and 30%) of ulexites having different particle sizes (45 and 75µm). The characterizations of  the prepared IPP based composites containing ulexite were performed by means of conventional measurement methods such as Differential Scanning Calorimeter (DSC), X-ray diffractions and several mechanical tests. The obtained results depicted that the content and particle size of boron mineral presenting in IPP based composites had significant effects on the crucial properties of IPP. Namely, the crystalline melting temperature of IPP increased initially (165.46°C to 168.54°C) when adding 5% of 45µm ulexite into IPP and then, dramatic decrease was observed with the content increment. The addition of 75µm ulexite into to IPP matrix led to consistent decreasing of crystalline melting temperatures of IPP domains. Furthermore, a and b unit cell dimensions of monoclinic structures initially showed the expansions, but then contracted consistently with the increasing of ulexite content. The serious decrement in c unit cell parameter was observed with the increasing of ulexite content for the both particle sizes.Moreover, the remarkable reinforcements were achieved in the ultimate strengths, Young's Modulus and impact strength of the IPP based composites. The maximum improvements in mechanical properties were obtained with the composites containing 5% of 45µm ulexite and mainly 15% of 75µm ulexite. These developments presumably were caused from advance in the alignments and orientations of the IPP chains in the matrix due to presence of ulexite particles.


ulexite, boron mineral, size effect, IPP based composites, thermal properties, unit cell parameters, mechanical reinforcement
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Primary Language en
Subjects Materials Science, Multidisciplinary
Published Date February 2020
Journal Section Research Articles
Authors

Orcid: 0000-0002-9244-026X
Author: Uğur SOYKAN (Primary Author)
Institution: ABANT IZZET BAYSAL UNIVERSITY, YENİÇAĞA YAŞAR ÇELİK VOCATIONAL SCHOOL
Country: Turkey


Supporting Institution Bolu Abant Izzet Baysal University
Thanks This work was supported by department of chemistry at Bolu Abant Izzet Baysal University (BAIBU). Furthermore, the authors especially thanks to chemistry department of Middle East Technical University and Innovative Food Technologies Development Application and Research Center (YENIGIDAM) for valuable supports.
Dates

Application Date : October 5, 2019
Acceptance Date : December 10, 2019
Publication Date : February 1, 2020

Bibtex @research article { saufenbilder629629, journal = {Sakarya University Journal of Science}, issn = {1301-4048}, eissn = {2147-835X}, address = {}, publisher = {Sakarya University}, year = {2020}, volume = {24}, pages = {205 - 219}, doi = {10.16984/saufenbilder.629629}, title = {Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP}, key = {cite}, author = {SOYKAN, Uğur} }
APA SOYKAN, U . (2020). Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP. Sakarya University Journal of Science , 24 (1) , 205-219 . DOI: 10.16984/saufenbilder.629629
MLA SOYKAN, U . "Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP". Sakarya University Journal of Science 24 (2020 ): 205-219 <http://www.saujs.sakarya.edu.tr/en/issue/49430/629629>
Chicago SOYKAN, U . "Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP". Sakarya University Journal of Science 24 (2020 ): 205-219
RIS TY - JOUR T1 - Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP AU - Uğur SOYKAN Y1 - 2020 PY - 2020 N1 - doi: 10.16984/saufenbilder.629629 DO - 10.16984/saufenbilder.629629 T2 - Sakarya University Journal of Science JF - Journal JO - JOR SP - 205 EP - 219 VL - 24 IS - 1 SN - 1301-4048-2147-835X M3 - doi: 10.16984/saufenbilder.629629 UR - https://doi.org/10.16984/saufenbilder.629629 Y2 - 2019 ER -
EndNote %0 Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP %A Uğur SOYKAN %T Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP %D 2020 %J Sakarya University Journal of Science %P 1301-4048-2147-835X %V 24 %N 1 %R doi: 10.16984/saufenbilder.629629 %U 10.16984/saufenbilder.629629
ISNAD SOYKAN, Uğur . "Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP". Sakarya University Journal of Science 24 / 1 (February 2020): 205-219 . https://doi.org/10.16984/saufenbilder.629629
AMA SOYKAN U . Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP. SAUJS. 2020; 24(1): 205-219.
Vancouver SOYKAN U . Role of boron mineral size on thermal, microstructural and mechanical characteristic of IPP. Sakarya University Journal of Science. 2020; 24(1): 219-205.