Year 2013, Volume 17 , Issue 1, Pages 17 - 26 2013-04-01

Hollow Fiber Liquid Phase Microextraction
Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon

Erol Alver [1] , Ayla Demirci [2] , Mustafa Özcimder [3]


Even though high precision analytical devices are developed in qualitative and quantitative determination of substance or substances in matrix samples (biological, environmental, food etc.), analytical devices mostly fail determining in matrix environment. Due to such reasons, clean-up process is needed to take (purification) and concentrate (enrichment) the substance in matrix environment. Liquid-liquid (LLE) extraction is commonly used in preparation of the samples. In recent years, liquid phase micro extraction (LPME) methods minimizing organic solvent used in liquidliquid extraction are developed. Of these methods, hollow fiber liquid phase micro extraction (HF–LPME) is widely used.
Even though high precision analytical devices are developed in qualitative and quantitative determination of substance or substances in matrix samples (biological, environmental, food etc.), analytical devices mostly fail determining in matrix environment. Due to such reasons, clean-up process is needed to take (purification) and concentrate (enrichment) the substance in matrix environment. Liquid-liquid (LLE) extraction is commonly used in preparation of the samples. In recent years, liquid phase micro extraction (LPME) methods minimizing organic solvent used in liquid-liquid extraction are developed. Of these methods, hollow fiber liquid phase micro extraction (HFLPME) is widely used.
  • Pestisit Su İkili Faz GC-MS 1 Pestisit Deniz suyu İkili Faz GC-MS Pestisit Sebze Üçlü Faz LC-MS 2 İnsektisit Su İkili Sistem GC-FTD 3 PAH Su İkili Faz GC-MS PAH Su Tepe Boşluklu GC-MS PAH Su, Toprak Üçlü Faz GC-FID 4 PAH Toprak İkili Faz GC-FID PAH Çam İğnesi İkili Faz GC-MS PAH Atık Su İkili faz GC-MS Fenoksi Herbisit İnek Sütü Üçlü Faz HPLC-UV 5 Triazin Herbisit Toprak İkili faz GC-MS Fungusit Portakal Suyu Üçlü Faz LC-MS Fenolik Asit Meyve Suyu Üçlü Faz HPLC-DAD 6 Nitrofenol Deniz Suyu Üçlü Faz LC-UV Fenol Su Üçlü Faz CE(MEKC) 7 Fenol Deniz suyu İkili faz GC-MS Aromatik amin Su Üçlü Faz CE Aromatik amin Su Üçlü Faz HPLC Florokinolon Su, Hayvan İdrarı Üçlü Faz HPLC-DAD/FD 8 Sülfonamit Su Üçlü Faz HPLC-DAD/FD İlaç İdrar, Plazma Üçlü Faz HPLC-UV İlaç İdrar, Plazma Üçlü Faz ESI-IMS 9 İlaç Kan Üçlü Faz LC-MS İlaç Arıtma Çamuru Üçlü Faz LC-MS İlaç Atık Su Üçlü Faz LC-MS-MS İlaç Su, Plazma Üçlü Faz CE İlaç İdrar, Plazma Üçlü Faz CE İlaç İdrar,Su Üçlü Faz CE-DAD/UV 10 Pb, Ni Su İkili Faz ETAAS 11 Cu, Zn, Pd, Cd, Hg, Pb, Bi Serum As(III), As(V) İçme Suyu, Saç İkili Faz ETAAS Uçuçu Selenyum Bileşikleri Su, toprak Metil-Hg Saç, Çamur İkili Faz GFAAS 13 1) GC-MS: Gaz Kromatograf- Kütle Spektrometresi 2) LC-MS: Sıvı Kromatograf- Kütle Spektrometresi 3) GC-FTD: Gaz Kromatograf-Termiyonik Detektör (Nitrojen-Fosfor Detektör, NPD) 4) GC-FID: Gaz Kromatograf-Alev İyonlaşma Detektörü 5) HPLC-UV: Yüksek Basınç Sıvı Kromatograf-UV Detektör 6) HPLC-DAD: Yüksek Basınç Sıvı Kromatograf-Diode Array Detektör 7) MEKC: Misel Elektrokinetik Kromatografi 8) HPLC-DAD/FD: Yüksek Basınç Sıvı Kromatograf-Diode Array/Floresan Detektör 9) ESI-IMS: Elektrosprey İyonizasyon-İyon Mobilite Spektrometresi 10) CE-DAD/Kapiler Elektroforez- Diode Array/UV Detektör 11) ETAAS: Elektrotermal Atomik Absorpsion Spektrometresi 12) ETV-ICP/MS: Elektrotermal Buharlaşma-İndüktif Optik Plazma Kütle Spektrometresi 13) GFAAS: Grafit Fırınlı Atomik Absorpsion Spektrometresi SONUÇ HF–LPME basit, hızlı, ucuz ve yüksek oranda seçici ve yüksek zenginleştirme faktörüne sahip bir yöntemdir. Oyuk fiber mikroekstraksiyon yöntemi çevresel, biyolojik, gıda örneklerinde ve asidik ve bazik ilaç analizlerinde zenginleştirmenin yanı sıra ön temizleme işlemini de aynı anda yaparak kullanılabilir. Fiber, alıcı fazın örnek çözelti ile doğrudan temasnı kestiğinden dolayı, şiddetli karıştırma hızlarında ekstraksiyon çözücüsü kaybını en az düzeylere indirir. Polipropilen fiber çok ucuz bir maliyete sahiptir. Bu nedenle, her analizde bir kez kullanılır. Fiberin her analizde bir kez kullanılması, önceki analizlerden kirlilik gelmesini engeller. Polipropilen hollow fiber küçük gözeneklere sahip olduğu için, matriks ortamdaki büyük molekül ağırlıklı kirliliklerin alıcı faza girmesini engelleyerek iyi bir ön temizleme işlemi yapar [2,13,22,29,67,71]. Yöntem, alıcı faz ile verici faz arasındaki membran bariyerin ekstraksiyon etkinliğini azaltması ve ekstraksiyon süresini uzatması, fiberin yüzeyinde hava kabarcıklarının oluşması ile ekstraksiyon etkinliği ve yinelenebilirliğin azaltması, gerçek örnek analizlerinde matriksin (kan, plazma, atık su) fiber üzerindeki gözenekleri tıkayabilmesi gibi dezavantajlara sahiptir [22,72,73]. KAYNAKLAR Krylov, V.A., Krylov, A.V, Mosyagin, P.V., Matkivskaya, Y.O., “Liquid–Phase Microextraction Preconcentration of Impurities”, Journal of Analytical Chemistry, 66, 331–350, (2011).
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Primary Language tr
Subjects Engineering
Published Date Nisan
Journal Section Research Articles
Authors

Author: Erol Alver

Author: Ayla Demirci

Author: Mustafa Özcimder

Dates

Application Date : May 16, 2012
Acceptance Date : December 23, 2012
Publication Date : April 1, 2013

Bibtex @research article { saufenbilder220539, journal = {Sakarya University Journal of Science}, issn = {1301-4048}, eissn = {2147-835X}, address = {}, publisher = {Sakarya University}, year = {2013}, volume = {17}, pages = {17 - 26}, doi = {10.16984/saufbed.30590}, title = {Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon}, key = {cite}, author = {Alver, Erol and Demirci, Ayla and Özcimder, Mustafa} }
APA Alver, E , Demirci, A , Özcimder, M . (2013). Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. Sakarya University Journal of Science , 17 (1) , 17-26 . Retrieved from http://www.saujs.sakarya.edu.tr/en/issue/20670/220539
MLA Alver, E , Demirci, A , Özcimder, M . "Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon". Sakarya University Journal of Science 17 (2013 ): 17-26 <http://www.saujs.sakarya.edu.tr/en/issue/20670/220539>
Chicago Alver, E , Demirci, A , Özcimder, M . "Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon". Sakarya University Journal of Science 17 (2013 ): 17-26
RIS TY - JOUR T1 - Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon AU - Erol Alver , Ayla Demirci , Mustafa Özcimder Y1 - 2013 PY - 2013 N1 - DO - T2 - Sakarya University Journal of Science JF - Journal JO - JOR SP - 17 EP - 26 VL - 17 IS - 1 SN - 1301-4048-2147-835X M3 - UR - Y2 - 2012 ER -
EndNote %0 Sakarya Üniversitesi Fen Bilimleri Enstitüsü Dergisi Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon %A Erol Alver , Ayla Demirci , Mustafa Özcimder %T Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon %D 2013 %J Sakarya University Journal of Science %P 1301-4048-2147-835X %V 17 %N 1 %R %U
ISNAD Alver, Erol , Demirci, Ayla , Özcimder, Mustafa . "Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon". Sakarya University Journal of Science 17 / 1 (April 2013): 17-26 .
AMA Alver E , Demirci A , Özcimder M . Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. SAUJS. 2013; 17(1): 17-26.
Vancouver Alver E , Demirci A , Özcimder M . Oyuk (Hollow) Fiber Sıvı Faz Mikroekstraksiyon. Sakarya University Journal of Science. 2013; 17(1): 26-17.